CO2 fixation by dicopper(II) complexes in hypodentate framework of N8O2

Yi-Hsueh Ho; Mu-Chieh Chang; Kuo-Hsuan Yu; Yi-Hung Liu; Yu Wang; Yuan-Chung Cheng; Jwu-Ting Chen

doi:10.1039/C3DT53497A

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

CO₂ fixation by dicopper(ii) complexes in hypodentate framework of N₈O₂†

Yi-Hsueh Ho,^a Mu-Chieh Chang,^a Kuo-Hsuan Yu,^a Yi-Hung Liu,^a Yu Wang,^a Yuan-Chung Cheng*^a and Jwu-Ting Chen*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, National Taiwan University, Taipei 106, Taiwan
E-mail: jtchen@ntu.edu.tw
Tel: +886 233661659

Abstract

A new ligand with N₈O₂ donors containing three potential metal-binding sites (H₂L) and its tricopper(II) complex 1 are synthesized. The tricopper species is found to be formed from a hypodentate dicopper(II) complex 2 in basic solutions. Complex 2 may be isolated from the reaction of H₂L with a copper source under acidic conditions. Complex 2 can undergo CO₂-abstraction to yield an octacopper(II) complex 3. The single crystal structures of complexes 2 and 3 are characterized by X-ray crystallography.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C3DT53497A
Article type: Communication
Submitted: 13 Dec 2013
Accepted: 28 Jan 2014
First published: 30 Jan 2014

Download Citation

Dalton Trans., 2014,43, 6287-6290

Permissions

Request permissions

CO₂ fixation by dicopper(II) complexes in hypodentate framework of N₈O₂

Y. Ho, M. Chang, K. Yu, Y. Liu, Y. Wang, Y. Cheng and J. Chen, Dalton Trans., 2014, 43, 6287 DOI: 10.1039/C3DT53497A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Dalton Transactions