Issue 17, 2014
From the journal:

Dalton Transactions

A hybrid vanadium fluoride with structurally isolated S = 1 kagome layers†

Farida H. Aidoudi,a   Lewis J. Downie,a   Russell E. Morris,a   Mark A. de Vriesb  and  Philip Lightfoot*a  

* Corresponding authors

a EaStChem, School of Chemistry, University of St Andrews, St Andrews, Fife KY16 9ST, UK

b EaStChem, School of Chemistry, University of Edinburgh, EH9 3JZ, UK
E-mail: pl@st-and.ac.uk

Abstract

A new organically-templated vanadium(III) fluoride, (NH4)2(C2H8N)[V3F12], has been prepared using an ionothermal approach. This compound has a unique layered structure featuring distorted S = 1 kagome planes separated by the cationic species. The compound exhibits magnetic frustration, with a canted antiferromagnetic ground state. On further cooling in the ground state a pronounced change in magnetisation kinetics is observed.

Graphical abstract: A hybrid vanadium fluoride with structurally isolated S = 1 kagome layers

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Article information

DOI
https://doi.org/10.1039/C4DT00452C
Article type
Communication
Submitted
12 Feb 2014
Accepted
13 Feb 2014
First published
13 Feb 2014

Dalton Trans., 2014,43, 6304-6307

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A hybrid vanadium fluoride with structurally isolated S = 1 kagome layers

F. H. Aidoudi, L. J. Downie, R. E. Morris, M. A. de Vries and P. Lightfoot, Dalton Trans., 2014, 43, 6304 DOI: 10.1039/C4DT00452C

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