Issue 45, 2014

Structural and magnetic studies of perovskite YCr0.5Mn0.5O3

Abstract

The structure of YCr0.5Mn0.5O6, established from Rietveld refinement of powder neutron diffraction data, contains Cr and Mn that are disordered on the octahedral sites. The structure is best described in the orthorhombic space group Pbnm. Low temperature neutron diffraction data reveal a G-type antiferromagnetic type arrangement, with a ferromagnetic component along the b-axis, indicating that the Cr and Mn couple ferro (or possibly ferri) magnetically to each other.

Graphical abstract: Structural and magnetic studies of perovskite YCr0.5Mn0.5O3

Article information

Article type
Paper
Submitted
17 Aug 2014
Accepted
22 Sep 2014
First published
22 Sep 2014

Dalton Trans., 2014,43, 17085-17089

Author version available

Structural and magnetic studies of perovskite YCr0.5Mn0.5O3

H. James, B. J. Kennedy, T. A. Whittle and M. Avdeev, Dalton Trans., 2014, 43, 17085 DOI: 10.1039/C4DT02503B

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