Issue 4, 2014
From the journal:

New Journal of Chemistry

Synthesis of a novel hybrid metal–organic salt and its solid-state transformation†

Javier Martí-Rujas*a  and  Massimo Camettib  

* Corresponding authors

a Center for Nano Science and Technology@Polimi, Istituto Italiano di Tecnologia, Via Pascoli 70/3, 20133 Milano, Italy
E-mail: javier.rujas@iit.it
Tel: +39022399 9829

b Department of Chemistry, Materials and Chemical Engineering “Giulio Natta”, Politecnico di Milano, Via L. Mancinelli 7, 20131 Milan, Italy

Abstract

A new non-centrosymmetric adamantanoid metal cluster has been synthesized by combining the macrocyclic K222 cryptand and ZnI2. Its solid-state crystal-to-polycrystalline transformation involves only the anionic adamantanoid cluster, while the cationic cryptand remains virtually unchanged as shown by single crystal and powder X-ray crystallography.

Graphical abstract: Synthesis of a novel hybrid metal–organic salt and its solid-state transformation

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Article information

DOI
https://doi.org/10.1039/C3NJ01400B
Article type
Letter
Submitted
12 Nov 2013
Accepted
10 Feb 2014
First published
10 Feb 2014

New J. Chem., 2014,38, 1385-1388

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Synthesis of a novel hybrid metal–organic salt and its solid-state transformation

J. Martí-Rujas and M. Cametti, New J. Chem., 2014, 38, 1385 DOI: 10.1039/C3NJ01400B

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