Issue 22, 2014
From the journal:

Organic & Biomolecular Chemistry

Gorlos-Phos for palladium-catalyzed borylation of aryl chlorides†

Pengbin Li,a   Chunling Fua  and  Shengming Ma*a  

* Corresponding authors

a Laboratory of Molecular Recognition and Synthesis, Department of Chemistry, Zhejiang University, Hangzhou 310027, Zhejiang, P. R. China
E-mail: masm@mail.sioc.ac.cn
Fax: (+86)21-6416-7510

Abstract

Using a readily available form of the mono-phosphine ligand, Gorlos-Phos·HBF4, Pd-catalyzed borylation of aryl chlorides afforded aryl boronates in high yields. A variety of functional groups are well compatible with this palladium catalyzed borylation reaction.

Graphical abstract: Gorlos-Phos for palladium-catalyzed borylation of aryl chlorides

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Article information

DOI
https://doi.org/10.1039/C4OB00293H
Article type
Paper
Submitted
08 Feb 2014
Accepted
20 Mar 2014
First published
25 Mar 2014

Org. Biomol. Chem., 2014,12, 3604-3610

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Gorlos-Phos for palladium-catalyzed borylation of aryl chlorides

P. Li, C. Fu and S. Ma, Org. Biomol. Chem., 2014, 12, 3604 DOI: 10.1039/C4OB00293H

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