Recent progress in the field of catalytic, enantioselective vinylogous Michael reactions of latent dienolates is described which furnish optically highly enriched chiral 1,7-dioxo compounds of great utility in one synthetic operation. Emphasis is given to new catalysis modes which realise this challenging transformation with high regio- as well as enantioselectivity.
C. Schneider and F. Abels, Org. Biomol. Chem., 2014, 12, 3531 DOI: 10.1039/C4OB00332B
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