The syntheses of α-ketoamides vianBu4NI-catalyzed multiple sp3C–H bond oxidation of ethylarenes and sequential coupling with dialkylformamides

Bingnan Du; Bo Jin; Peipei Sun

doi:10.1039/C4OB00520A

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The syntheses of α-ketoamides viaⁿBu₄NI-catalyzed multiple sp³C–H bond oxidation of ethylarenes and sequential coupling with dialkylformamides†

Bingnan Du,^a Bo Jin^a and Peipei Sun*^ab

Author affiliations

* Corresponding authors

^a Jiangsu Key Laboratory of Biofunctional Materials, College of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210097, China

^b Jiangsu Collaborative Innovation Center of Biomedical Functional Materials, Nanjing 210023, China
E-mail: sunpeipei@njnu.edu.cn
Fax: +86-25-85891767
Tel: +86-25-85891767

Abstract

The ⁿBu₄NI-catalyzed sequential C–O and C–N bond formation via multiple sp³C–H bond activation of ethylarenes, using N,N-dialkylformamide as the amino source, provided α-ketoamides with moderate yields.

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Article information

DOI: https://doi.org/10.1039/C4OB00520A
Article type: Communication
Submitted: 08 Mar 2014
Accepted: 09 May 2014
First published: 12 May 2014

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Org. Biomol. Chem., 2014,12, 4586-4589

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The syntheses of α-ketoamides viaⁿBu₄NI-catalyzed multiple sp³C–H bond oxidation of ethylarenes and sequential coupling with dialkylformamides

B. Du, B. Jin and P. Sun, Org. Biomol. Chem., 2014, 12, 4586 DOI: 10.1039/C4OB00520A

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Organic & Biomolecular Chemistry