TEMPO-mediated reactions of alkenyl hydrazones afforded azaheterocycles via sp3 C–H allylic amination. The transformation is featured by a sequence of remote allylic H-radical shift and allylic homolytic substitution with hydrazone radicals.
X. Zhu and S. Chiba, Org. Biomol. Chem., 2014, 12, 4567 DOI: 10.1039/C4OB00839A
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