Issue 36, 2014
From the journal:

Organic & Biomolecular Chemistry

A convenient tandem one-pot synthesis of donor–acceptor-type triphenylene 2,3-dicarboxylic esters from diarylacetylene†

Chun Feng,*a   Xian-Li Tian,a   Jing Zhou,a   Shi-Kai Xiang,a   Wen-Hao Yu,a   Bi-Qin Wang,*a   Ping Hu,a   Carl Redshawab  and  Ke-Qing Zhaoa  

* Corresponding authors

a College of Chemistry and Material Sciences, Sichuan Normal University, Chengdu, P.R. China
E-mail: feng_chun@126.com, wangbiqin1964@126.com

b Department of Chemistry, The University of Hull, Hull, HU6 7RX, UK

Abstract

A tandem one-pot method for the direct synthesis of polysubstituted triphenylene 2,3-dicarboxylic esters with different substitution patterns was developed by enyne metathesis of diarylacetylene, followed by Diels–Alder, aromatization and a cyclization cascade.

Graphical abstract: A convenient tandem one-pot synthesis of donor–acceptor-type triphenylene 2,3-dicarboxylic esters from diarylacetylene

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Article information

DOI
https://doi.org/10.1039/C4OB01503G
Article type
Communication
Submitted
17 Jul 2014
Accepted
29 Jul 2014
First published
29 Jul 2014

Org. Biomol. Chem., 2014,12, 6977-6981

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A convenient tandem one-pot synthesis of donor–acceptor-type triphenylene 2,3-dicarboxylic esters from diarylacetylene

C. Feng, X. Tian, J. Zhou, S. Xiang, W. Yu, B. Wang, P. Hu, C. Redshaw and K. Zhao, Org. Biomol. Chem., 2014, 12, 6977 DOI: 10.1039/C4OB01503G

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