A variety of ester enolate equivalents are generated in situ and undergo α-allylation in high yields via palladium-catalyzed decarboxylative allylation. The transformations are complete within very short reaction times under ambient conditions. Synthesis of α-allylated acyl derivatives provides access to other carboxylic acid and alcohol derivatives via acyl group substitution or reduction.
Y. Ariyarathna and J. A. Tunge, Org. Biomol. Chem., 2014, 12, 8386 DOI: 10.1039/C4OB01752H
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