A silver-mediated oxidative vinylic C–H bond sulfenylation of enamides was developed. This method is compatible with diaryl and dialkyl disulfides to deliver biologically precious chalcogenated olefins efficiently. A plausible non-chain radical mechanism was proposed for understanding this novel sulfenylation based on the mechanistic studies.
L. Yang, Q. Wen, F. Xiao and G. Deng, Org. Biomol. Chem., 2014, 12, 9519 DOI: 10.1039/C4OB01970A
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