Issue 11, 2014
From the journal:

Organic Chemistry Frontiers

The dicyclen–TPE zinc complex as a novel fluorescent ensemble for nanomolar pyrophosphate sensing in 100% aqueous solution†

Hao-Ran Xu,a   Kun Li,*a   Ming-Qi Wang,a   Bo-Lin Wang,a   Xin Wanga  and  Xiao-Qi Yu*a  

* Corresponding authors

a Key Laboratory of Green Chemistry and Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu, P. R. China
E-mail: kli@scu.edu.cn, xqyu@scu.edu.cn
Fax: +86-28-85415886

Abstract

A dicyclen–TPE Zn(II) complex was developed as a fluorescent ensemble for pyrophosphate (PPi) in water. The complex was characterized by X-ray single crystal diffraction, which could selectively respond to PPi over other phosphates with a large enhancement of fluorescence intensity, and the detection limit was determined to be 22.8 nM.

Graphical abstract: The dicyclen–TPE zinc complex as a novel fluorescent ensemble for nanomolar pyrophosphate sensing in 100% aqueous solution

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Article information

DOI
https://doi.org/10.1039/C4QO00243A
Article type
Research Article
Submitted
06 Sep 2014
Accepted
28 Oct 2014
First published
29 Oct 2014

Org. Chem. Front., 2014,1, 1276-1279

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The dicyclen–TPE zinc complex as a novel fluorescent ensemble for nanomolar pyrophosphate sensing in 100% aqueous solution

H. Xu, K. Li, M. Wang, B. Wang, X. Wang and X. Yu, Org. Chem. Front., 2014, 1, 1276 DOI: 10.1039/C4QO00243A

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