Issue 1, 2014
From the journal:

RSC Advances

Chlorotrimethylsilane (TMSCl): an efficient silicon-based Lewis acid mediator in allylic alkylation using a diethylzinc reagent†

Wen-Hui Deng,a   Fei Ye,a   Xing-Feng Bai,a   Li Li,*a   Tao Song,a   Yun-Long Weia  and  Li-Wen Xu*a  

* Corresponding authors

a Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, College of Material, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou 311121, P. R. China
E-mail: liwenxu@hznu.edu.cn, licpxulw@yahoo.com
Fax: +86 2886 5135
Tel: +86 2886 8915

Abstract

Chlorotrimethylsilane (TMSCl) was a highly efficient catalyst in the allylic alkylation of 1,3-diaryl-2-propenyl acetates with a diethylzinc reagent, in which various 1,3-diaryl-2-propenyl acetates are efficiently transferred to 1,3-diarylpent-1-enes in good to excellent yields.

Graphical abstract: Chlorotrimethylsilane (TMSCl): an efficient silicon-based Lewis acid mediator in allylic alkylation using a diethylzinc reagent

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Article information

DOI
https://doi.org/10.1039/C3RA44742A
Article type
Communication
Submitted
31 Aug 2013
Accepted
31 Oct 2013
First published
05 Nov 2013

RSC Adv., 2014,4, 479-483

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Chlorotrimethylsilane (TMSCl): an efficient silicon-based Lewis acid mediator in allylic alkylation using a diethylzinc reagent

W. Deng, F. Ye, X. Bai, L. Li, T. Song, Y. Wei and L. Xu, RSC Adv., 2014, 4, 479 DOI: 10.1039/C3RA44742A

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