Carbon dioxide absorption by hydroxyalkyl amidines impregnated into mesoporous silica: the effect of pore morphology and absorbent loading

Abstract

Hydroxyalkyl amidine (HAM) derivatives react with CO₂ in a quantitative manner under dry conditions near room temperature, and then release it at a moderate temperature of approximately 60 °C. In the present study, HAM compounds were impregnated into porous silica particles to obtain solid CO₂ sorbents. This process produced a large surface area for reaction between CO₂ and the absorbents for enhanced CO₂ capture efficiency. Several types of mesoporous silicas that differed in pore size, pore volume, and particle size and shape were investigated in order to identify the optimum processing parameters for preparation of hybrid materials with the best possible CO₂ capture performance. The amount of HAMs loaded into the silica was optimized so as to retain the open porous structure for efficient transport of gas molecules, while providing a large surface area of reactive material. We have demonstrated that HAM-loaded silica could be used as an effective CO₂ filter for dilute gas mixtures such as air.