Issue 10, 2014
From the journal:

RSC Advances

An NMR study on a pseudo-intramolecular transacylation reaction of an α-aryl-β-keto ester†

Sho Hirai,a   Haruyasu Asahara,a   Shotaro Hirao,a   Jun Sawayama,a   Ryuichi Sugimoto,a   Kazuhiko Saigoa  and  Nagatoshi Nishiwaki*a  

* Corresponding authors

a School of Environmental Science and Engineering, Kochi University of Technology, Tosayamada, Kami, Kochi 782-8502, Japan
E-mail: nishiwaki.nagatoshi@kochi-tech.ac.jp
Fax: +81 887 57 2520

Abstract

The pseudo-intramolecular transacylation reaction efficiently proceeds like an intramolecular reaction, even though it is actually an intermolecular reaction. We have obtained valuable insights by monitoring the reaction by 1H NMR spectroscopy.

Graphical abstract: An NMR study on a pseudo-intramolecular transacylation reaction of an α-aryl-β-keto ester

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Article information

DOI
https://doi.org/10.1039/C3RA45568H
Article type
Communication
Submitted
03 Oct 2013
Accepted
13 Nov 2013
First published
14 Nov 2013

RSC Adv., 2014,4, 4889-4892

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An NMR study on a pseudo-intramolecular transacylation reaction of an α-aryl-β-keto ester

S. Hirai, H. Asahara, S. Hirao, J. Sawayama, R. Sugimoto, K. Saigo and N. Nishiwaki, RSC Adv., 2014, 4, 4889 DOI: 10.1039/C3RA45568H

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