Issue 8, 2014
From the journal:

RSC Advances

An easy access to tertiary amides from aldehydes and N,N-dialkylchlorothiophosphoramidates†

Uma Pathak,*a   Shubhankar Bhattacharyya,a   Lokesh kumar Pandey,‡a   Sweta Mathur‡a  and  Rajeev Jainb  

* Corresponding authors

a Synthetic Chemistry Division, Defence R & D Establishment, Jhansi Road, Gwalior-474002, India
E-mail: sc_drde@rediffmail.com
Fax: +91-0751-2341148
Tel: +91-0751-2390189

b School of Studies in Chemistry, Jiwaji University, Gwalior-474002, India
E-mail: rajeevjain54@yahoo.co.in
Fax: +91-0751-2346209
Tel: +91-0751-2346209

Abstract

A mechanistically unprecedented approach for the formation of tertiary amides from N,N-dialkylchlorothiophosphoramidates and aldehydes has been developed. The reaction occurred via the activation of aldehydes with N,N-dialkylchlorothiophosphoramidates followed by amidation with dialkylamine pendent of the same phosphoramidate.

Graphical abstract: An easy access to tertiary amides from aldehydes and N,N-dialkylchlorothiophosphoramidates

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Article information

DOI
https://doi.org/10.1039/C3RA45781H
Article type
Communication
Submitted
12 Oct 2013
Accepted
24 Oct 2013
First published
31 Oct 2013

RSC Adv., 2014,4, 3900-3903

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An easy access to tertiary amides from aldehydes and N,N-dialkylchlorothiophosphoramidates

U. Pathak, S. Bhattacharyya, L. K. Pandey, S. Mathur and R. Jain, RSC Adv., 2014, 4, 3900 DOI: 10.1039/C3RA45781H

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