The total syntheses of rubiginone A2, C2 and fujianmycin A are described. The synthesis involves Diels–Alder/aromatization and photo chemical reactions as key steps to construct the tetracyclic frame of benz[a]anthraquinone skeleton. Sharpless epoxidation, a copper-catalyzed regioselective epoxide opening, and enyne metathesis reactions are utilized as the key steps for the synthesis of chiral vinylcyclohexene.
D. G. Vanga and K. P. Kaliappan, RSC Adv., 2014, 4, 12716 DOI: 10.1039/C3RA47775D
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