Issue 22, 2014
From the journal:

RSC Advances

Pd-catalyzed ligand-free Suzuki reaction of β-substituted allylic halides with arylboronic acids in water†

Chaonan Dong,a   Lingjuan Zhang,a   Xiao Xue,a   Huanrong Li,a   Zhiyong Yu,a   Weijun Tanga  and  Lijin Xu*a  

* Corresponding authors

a Department of Chemistry, Renmin University of China, Beijing, China
E-mail: xulj@chem.ruc.edu.cn

Abstract

The catalyst system consisting of Pd(TFA)2 and KOH allows for a wide range of β-substituted allylic halides to react efficiently with various arylboronic acids in neat water under ligand-free conditions, affording the allylated arenes in high yields with broad functional group tolerance and up to 7.4 × 105 TON and 15 416 h−1 TOF.

Graphical abstract: Pd-catalyzed ligand-free Suzuki reaction of β-substituted allylic halides with arylboronic acids in water

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Article information

DOI
https://doi.org/10.1039/C3RA47813K
Article type
Communication
Submitted
20 Dec 2013
Accepted
11 Feb 2014
First published
11 Feb 2014

RSC Adv., 2014,4, 11152-11158

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Pd-catalyzed ligand-free Suzuki reaction of β-substituted allylic halides with arylboronic acids in water

C. Dong, L. Zhang, X. Xue, H. Li, Z. Yu, W. Tang and L. Xu, RSC Adv., 2014, 4, 11152 DOI: 10.1039/C3RA47813K

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