A novel polymer synthetic method, the intrapolymer Heck reaction, provided ladder-type ionomer membranes with excellent proton conductivity (221 mS cm−1 at 80 °C and 90% relative humidity) and mechanical strength over a wide range of humidity (ca. 0–90% relative humidity) at 80 °C.
J. Miyake, M. Watanabe and K. Miyatake, RSC Adv., 2014, 4, 21049 DOI: 10.1039/C4RA02582B
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