Solvent-free coupling reactions of arylboronic acids with various amines were presented under ball milling conditions, achieving the aromatic amine coupling products with yields ranging from moderate to good. This type of mechano-chemistry exhibited advantages of solvent-free property, high efficiency, simple work-up procedure and eco-friendliness.
X. Zhu, Q. Zhang and W. Su, RSC Adv., 2014, 4, 22775 DOI: 10.1039/C4RA02952F
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