Mn2+ cation-directed ionothermal synthesis of an open-framework fluorinated aluminium phosphite–phosphate

Hao Liu; Zhi-Jian Tian; Hermann Gies; Ying Wei; Bernd Marler; Lei Wang; Ya-Song Wang; Da-Wei Li

doi:10.1039/C4RA05350H

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Mn²⁺ cation-directed ionothermal synthesis of an open-framework fluorinated aluminium phosphite–phosphate†

Hao Liu,^ab Zhi-Jian Tian,*^ac Hermann Gies,^d Ying Wei,^d Bernd Marler,^d Lei Wang,^a Ya-Song Wang^ab and Da-Wei Li^ab

Author affiliations

* Corresponding authors

^a Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China
E-mail: tianz@dicp.ac.cn
Fax: +86 411-843-79151

^b University of Chinese Academy of Sciences, Beijing, China

^c State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China

^d Institute for Geology, Mineralogy and Geophysics, Ruhr-University-Bochum, Bochum, Germany

Abstract

An open-framework fluorinated aluminium phosphite–phosphate, H_3.2Mn_3.4[C₆N₂H₁₁]₂{Al₁₂(HPO₃)_15.0(HPO₄)_3.0F₁₂}·14H₂O (DNL-2), was ionothermally synthesized by employing the in situ released Mn²⁺ cations as structure-directing agent.

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Article information

DOI: https://doi.org/10.1039/C4RA05350H
Article type: Communication
Submitted: 30 Apr 2014
Accepted: 23 Jun 2014
First published: 24 Jun 2014

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RSC Adv., 2014,4, 29310-29313

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Mn²⁺ cation-directed ionothermal synthesis of an open-framework fluorinated aluminium phosphite–phosphate

H. Liu, Z. Tian, H. Gies, Y. Wei, B. Marler, L. Wang, Y. Wang and D. Li, RSC Adv., 2014, 4, 29310 DOI: 10.1039/C4RA05350H

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