Click-based porous inorganic–organic hybrid material (PHM) containing cyclophosphazene unit and their application in carbon dioxide capture†
Abstract
Porous inorganic–organic hybrid material (PHM) have been synthesized by click chemistry with cyclophosphazene in the framework. PHM-1 is X-ray amorphous and has a high specific surface area of 453 m2 g−1 with a pore size distribution of 3.7 nm. It shows a reversible CO2 uptake of 1.83 mmol g−1 at 273 K.