Copper-catalyzed acyloxylation of the C(sp3)–H bond adjacent to an oxygen by a cross-dehydrogenative coupling approach

Kammari Bal Raju; Bejjanki Naveen Kumar; Kommu Nagaiah

doi:10.1039/C4RA06233G

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Copper-catalyzed acyloxylation of the C(sp³)–H bond adjacent to an oxygen by a cross-dehydrogenative coupling approach†

Kammari Bal Raju,^a Bejjanki Naveen Kumar^a and Kommu Nagaiah*^a

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* Corresponding authors

^a Organic & Biomolecular Chemistry Division, CSIR–Indian Institute of Chemical Technology, Tarnaka, Hyderabad, India
E-mail: nagaiah@iict.res.in
Fax: +91 40 27191659

Abstract

The acyloxylation of the C(sp³)–H bond adjacent to oxygen by adopting a copper catalyzed dehydrogenative cross-coupling reaction between simple ethers and benzyl alcohols has been disclosed. The advantages of the dehydrogenative cross-coupling reaction are the adoption of unactivated ethers as substrates and good tolerance of many functional groups.

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Article information

DOI: https://doi.org/10.1039/C4RA06233G
Article type: Communication
Submitted: 02 Jul 2014
Accepted: 22 Sep 2014
First published: 23 Sep 2014

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RSC Adv., 2014,4, 50795-50800

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Copper-catalyzed acyloxylation of the C(sp³)–H bond adjacent to an oxygen by a cross-dehydrogenative coupling approach

K. B. Raju, B. N. Kumar and K. Nagaiah, RSC Adv., 2014, 4, 50795 DOI: 10.1039/C4RA06233G

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