Issue 81, 2014

Iridium–CNP complex catalyzed cross-coupling of primary alcohols and secondary alcohols by a borrowing hydrogen strategy

Abstract

A highly efficient C–C bond formation has been developed through the cross-coupling of primary and secondary alcohols. The corresponding functionalized ketones were obtained with an iridium–CNP complex as a catalyst through the borrowing hydrogen strategy. The present methodology provides an easy alternative method to aldol reaction derivatives. More importantly, the complexes were also effective catalysts for the alkylation of an aromatic amine with a tertiary alkyl amine.

Graphical abstract: Iridium–CNP complex catalyzed cross-coupling of primary alcohols and secondary alcohols by a borrowing hydrogen strategy

Supplementary files

Article information

Article type
Communication
Submitted
01 Jul 2014
Accepted
29 Aug 2014
First published
29 Aug 2014

RSC Adv., 2014,4, 42924-42929

Iridium–CNP complex catalyzed cross-coupling of primary alcohols and secondary alcohols by a borrowing hydrogen strategy

D. Wang, K. Zhao, X. Yu, H. Miao and Y. Ding, RSC Adv., 2014, 4, 42924 DOI: 10.1039/C4RA06474G

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