An efficient method of palladium-catalyzed direct arylation has been developed for the selective functionalization of the C6 position of 2,4-diarylpyrrolo[2,3-d]pyrimidines. Under optimal conditions, various aryl bromides successfully provided a wide range of 6-arylpyrrolo[2,3-d]pyrimidines.
![Graphical abstract: Access to 6-arylpyrrolo[2,3-d]pyrimidines via a palladium-catalyzed direct C–H arylation reaction](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C4RA07088G&imageInfo.ImageIdentifier.Year=2014)
J. Dodonova and S. Tumkevicius, RSC Adv., 2014, 4, 35966 DOI: 10.1039/C4RA07088G
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