Issue 89, 2014

Synthesis of oxazolidinofullerenes/thiazolidinofullerenes: novel reaction of [60]fullerene with isocyanates/isothiocyanates promoted by ferric perchlorate

Abstract

The facile one-step reaction of [60]fullerene with isocyanates/isothiocyanates in the presence of ferric perchlorate generates a series of oxazolidinofullerenes/thiazolidinofullerenes, which are difficult to prepare by common methods. The direct dissolution approach plays an important role in the efficient synthesis of oxazolidinofullerenes/thiazolidinofullerenes. A possible reaction mechanism for the product formation is proposed.

Graphical abstract: Synthesis of oxazolidinofullerenes/thiazolidinofullerenes: novel reaction of [60]fullerene with isocyanates/isothiocyanates promoted by ferric perchlorate

Supplementary files

Article information

Article type
Paper
Submitted
03 Aug 2014
Accepted
23 Sep 2014
First published
23 Sep 2014

RSC Adv., 2014,4, 48085-48094

Author version available

Synthesis of oxazolidinofullerenes/thiazolidinofullerenes: novel reaction of [60]fullerene with isocyanates/isothiocyanates promoted by ferric perchlorate

F. Li, Y. Zhu, X. Zhang, J. Shi, J. Wu, L. Chen, X. Liang and L. Liu, RSC Adv., 2014, 4, 48085 DOI: 10.1039/C4RA10199E

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