A novel Cu-catalyzed direct alkenylation of simple alkanes with styrenes was described. In the presence of a catalytic amount of Cu(OTf)2, a diverse range of alkenes undergo coupling with cycloalkanes to produce (E)-alkyl alkenes. This transformation is proposed to proceed via a radical process.
Y. Zhu and Y. Wei, Chem. Sci., 2014, 5, 2379 DOI: 10.1039/C4SC00093E
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