Issue 5, 2014
From the journal:

Journal of Materials Chemistry A

Alumina-supported cobalt–adeninate MOF membranes for CO2/CH4 separation†

Zhenzhen Xie,‡a   Tao Li,‡b   Nathaniel L. Rosi*b  and  Moises A. Carreon*a  

* Corresponding authors

a Department of Chemical Engineering, University of Louisville, Louisville, Kentucky, USA
E-mail: macarr15@louisville.edu
Fax: +1 502-852-6355
Tel: +1 502-852-4103

b Department of Chemistry, University of Pittsburgh, 219 Parkman Ave., Pittsburgh, Pennsylvania 15260, USA
E-mail: nrosi@pitt.edu
Fax: +1 412-624-8611
Tel: +1 412-624-3987

Abstract

The synthesis of continuous cobalt–adeninate MOF (bio-MOF-13 (I) and bio-MOF-14 (II)) membranes supported on porous alumina tubes is demonstrated. The membranes showed high CO2 permeabilities and low to moderate CO2 separation selectivities for CO2/CH4 gas mixtures. The observed CO2/CH4 selectivities are attributed to preferential CO2 adsorption within the framework.

Graphical abstract: Alumina-supported cobalt–adeninate MOF membranes for CO2/CH4 separation

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Article information

DOI
https://doi.org/10.1039/C3TA14058J
Article type
Communication
Submitted
09 Oct 2013
Accepted
24 Nov 2013
First published
25 Nov 2013

J. Mater. Chem. A, 2014,2, 1239-1241

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Alumina-supported cobalt–adeninate MOF membranes for CO2/CH4 separation

Z. Xie, T. Li, N. L. Rosi and M. A. Carreon, J. Mater. Chem. A, 2014, 2, 1239 DOI: 10.1039/C3TA14058J

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