Issue 8, 2014
From the journal:

Journal of Materials Chemistry C

Highly efficient photoluminescent Cu(i)–PyrPHOS-metallopolymers†

Daniel Volz,abe   Astrid F. Hirschbiel,cd   Daniel M. Zink,e   Jana Friedrichs,e   Martin Nieger,f   Thomas Baumann,*e   Stefan Bräse*ab  and  Christopher Barner-Kowollik*cd  

* Corresponding authors

a Institute of Organic Chemistry, Karlsruhe Institute of Technology (KIT), Fritz-Haber-Weg 6, 76131 Karlsruhe, Germany
E-mail: braese@kit.edu

b Institute of Toxicology and Genetics, Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

c Preparative Macromolecular Chemistry, Institute of Chemical Technology and Polymer Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstr. 18, 76131 Karlsruhe, Germany
E-mail: christopher.barner-kowollik@kit.edu

d Institute for Biological Interfaces, Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

e cynora GmbH, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany
E-mail: info@cynora.com

f Laboratory of Inorganic Chemistry, University of Helsinki, P.O. Box 55, Finland

Abstract

The photoluminescence quantum efficiency as well as the processing properties of a series of brightly luminescent Cu(I)-metallopolymers strongly depended on the chosen synthetic approach. A monomeric, substituted styrenic complex features a photoluminescence quantum efficiency (PLQY) of only 4%, while its metallopolymeric thin film is over one order of magnitude more efficient.

Graphical abstract: Highly efficient photoluminescent Cu(i)–PyrPHOS-metallopolymers

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Article information

DOI
https://doi.org/10.1039/C3TC32347A
Article type
Paper
Submitted
27 Nov 2013
Accepted
03 Dec 2013
First published
04 Dec 2013

J. Mater. Chem. C, 2014,2, 1457-1462

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Highly efficient photoluminescent Cu(I)–PyrPHOS-metallopolymers

D. Volz, A. F. Hirschbiel, D. M. Zink, J. Friedrichs, M. Nieger, T. Baumann, S. Bräse and C. Barner-Kowollik, J. Mater. Chem. C, 2014, 2, 1457 DOI: 10.1039/C3TC32347A

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