The isomers of xylene have been separated by enclathration using three host compounds: 9,9′-bianthryl (H1), 9,9′-spirobifluorene (H2) and trans-2,3-dibenzoylspiro[cyclopropane-1,9-fluorene] (H3). The structures of each host with a single xylene isomer have been elucidated and, for H1, the relative lattice energies of the clathrates with ortho- and para-xylene have been evaluated.
L. R. Nassimbeni, N. B. Báthori, L. D. Patel, H. Su and E. Weber, Chem. Commun., 2015, 51, 3627 DOI: 10.1039/C4CC05329J
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