The first highly regioselective and general osmium-catalyzed hydroformylation of olefins to aldehydes is reported. The combination of Os3(CO)12 and imidazoyl-substituted phosphine ligands allows n-selective (up to 99%) hydroformylation of bulk aliphatic as well as functional alkenes in good yields (64–87%).
L. Wu, Q. Liu, A. Spannenberg, R. Jackstell and M. Beller, Chem. Commun., 2015, 51, 3080 DOI: 10.1039/C4CC05626D
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