The development of a Mn–salen complex catalysed oxidative benzylic fluorination of non-activated C–H bonds using [18F]fluoride is described for installation of [18F]CHRF, [18F]CR2F and particularly [18F]CF3 containing groups in the presence of other functional groups.
![Graphical abstract: Mn–salen catalysed benzylic C–H activation for the synthesis of aryl [18F]CF3-containing PET probes](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C4CC05762G&imageInfo.ImageIdentifier.Year=2015)
L. Carroll, H. L. Evans, A. C. Spivey and E. O. Aboagye, Chem. Commun., 2015, 51, 8439 DOI: 10.1039/C4CC05762G
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