Issue 25, 2015
From the journal:

Chemical Communications

Is it possible to achieve a complete desaturation of cycloalkanes promoted by o-benzyne?†

Francisco Cervantes-Navarro,a   Abel de Cózar,bcd   Fernando P. Cossío,*bc   María A. Fernández-Herrera,*a   Gabriel Merino*a  and  Israel Fernández*e  

* Corresponding authors

a Departamento de Física Aplicada, Centro de Investigación y de Estudios Avanzados Unidad Mérida, km 6 Antigua carretera a Progreso. Apdo. Postal 73, Cordemex, Mérida, Yuc., México
E-mail: mfernandez@mda.cinvestav.mx, gmerino@mda.cinvestav.mx

b Departamento de Química Orgánica I-Kimika Organikoa I Saila, Facultad de Química-Kimika Fakultatea, Universidad del País Vasco-Euskal Herriko Unibertsitatea, P. K. 1072, E-20080 San Sebastián-Donostia, Spain

c Donostia International Physics Center (DIPC), P.O. 1072, 20018 San Sebastián-Donostia, Spain
E-mail: fp.cossio@ehu.es

d IKERBASQUE, Basque Foundation for Science, Bilbao, Spain

e Departamento de Química Orgánica I, Facultad de Ciencias Químicas, Universidad Complutense, E-28040 Madrid, Spain
E-mail: israel@quim.ucm.es

Abstract

The competence between the possible reaction pathways in the reaction of different cycloalkanes and o-benzyne has been computationally explored. Systems able to undergo complete desaturation by consecutive double hydrogen atom transfer reactions are suggested.

Graphical abstract: Is it possible to achieve a complete desaturation of cycloalkanes promoted by o-benzyne?

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Article information

DOI
https://doi.org/10.1039/C4CC07311H
Article type
Communication
Submitted
16 Sep 2014
Accepted
23 Oct 2014
First published
23 Oct 2014

Chem. Commun., 2015,51, 5302-5305

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Is it possible to achieve a complete desaturation of cycloalkanes promoted by o-benzyne?

F. Cervantes-Navarro, A. de Cózar, F. P. Cossío, M. A. Fernández-Herrera, G. Merino and I. Fernández, Chem. Commun., 2015, 51, 5302 DOI: 10.1039/C4CC07311H

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