Synthesis of unsymmetrical N-carboranyl NHCs: directing effect of the carborane anion†
Abstract
The syntheses of unsymmetrical N-heterocyclic carbenes (NHCs) that contain a single N-bound icosahedral carborane anion substituent are reported. Both anionic C-2 and doubly deprotonated dianionic C-2/C-5 NHC lithium complexes are isolated. The latter species is formed selectively, which reveals a surprising directing effect conveyed by icosahedral carborane anion substituents.
- This article is part of the themed collection: 2015 Emerging Investigators