Alkyl-substituted tetra-coordinate organoboronium bisdiketone complexes exhibit dramatic luminescence thermochromism in organic solvents. In glass-forming alcohols, these complexes exhibit a reversible aqua blue to orange-red to greenish yellow luminescence emission colour change upon cooling.
X. Chen, X. Zhang and G. Zhang, Chem. Commun., 2015, 51, 161 DOI: 10.1039/C4CC08289C
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