Issue 6, 2015
From the journal:

Chemical Communications

Phosphine-catalyzed dearomatizing [3+2] annulations of isoquinolinium methylides with allenes†

Zhi-Jun Jia,ab   Constantin Gabriel Daniliuc,c   Andrey P. Antonchick*ab  and  Herbert Waldmann*ab  

* Corresponding authors

a Max-Planck-Institut für Molekulare Physiologie, Abteilung Chemische Biologie, Otto-Hahn-Strasse 11, 44227 Dortmund, Germany
E-mail: Andrey.Antonchick@mpi-dortmund.mpg.de, Herbert.Waldmann@mpi-dortmund.mpg.de

b Technische Universität Dortmund, Fakultät Chemie und Chemische Biologie, Chemische Biologie, Otto-Hahn-Strasse 6, 44227 Dortmund, Germany

c Organisch-Chemisches Institut, Universität Münster, Corrensstrasse 40, 48149 Münster, Germany

Abstract

A phosphine-catalyzed dearomatizing [3+2] annulation of isoquinolinium methylides with allenoates or allenones yields highly functionalized pyrroloisoquinolines with high regioselectivity and in viable yields.

Graphical abstract: Phosphine-catalyzed dearomatizing [3+2] annulations of isoquinolinium methylides with allenes

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Article information

DOI
https://doi.org/10.1039/C4CC08555H
Article type
Communication
Submitted
29 Oct 2014
Accepted
26 Nov 2014
First published
26 Nov 2014

Chem. Commun., 2015,51, 1054-1057

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Phosphine-catalyzed dearomatizing [3+2] annulations of isoquinolinium methylides with allenes

Z. Jia, C. G. Daniliuc, A. P. Antonchick and H. Waldmann, Chem. Commun., 2015, 51, 1054 DOI: 10.1039/C4CC08555H

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