Issue 25, 2015
From the journal:

Chemical Communications

Neptunyl(vi) centred visible LMCT emission directly observable in the presence of uranyl(vi)†

Sean D. Woodall,a   Adam N. Swinburne,ab   Nidhu lal Banik,c   Andrew Kerridge,‡e   Poppy Di Pietro,e   Christian Adam,cd   Peter Kadenc  and  Louise S. Natrajan*ab  

* Corresponding authors

a The Centre for Radiochemistry Research, The School of Chemistry, The University of Manchester, Oxford Road, Manchester, UK
E-mail: louise.natrajan@manchester.ac.uk
Tel: +44 (0)1612751426

b The Photon Science Institute, Alan Turing Building, The University of Manchester, Oxford Road, Manchester, UK

c Karlsruhe Institute of Technology (KIT), Institute for Nuclear Waste Disposal (INE), P.O. Box 3640, 76021 Karlsruhe, Germany

d University of Heidelberg, Institute for Physical Chemistry, Im Neuenheimer Feld 253, 69120 Heidelberg, Germany

e Department of Chemistry, University College London, 20 Gordon Street, London, UK

Abstract

Room temperature detection of neptunyl(VI) LMCT emission in a coordination compound and in the presence of uranyl(VI) is reported for the first time. Differences in the excitation profiles of the complexes enable spectral editing so either exclusively neptunyl(VI) or uranyl(VI) emission is observed or a sum of the two.

Graphical abstract: Neptunyl(vi) centred visible LMCT emission directly observable in the presence of uranyl(vi)

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Article information

DOI
https://doi.org/10.1039/C4CC08718F
Article type
Communication
Submitted
02 Nov 2014
Accepted
16 Dec 2014
First published
16 Dec 2014
This article is Open Access
Creative Commons BY license

Chem. Commun., 2015,51, 5402-5405

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Neptunyl(VI) centred visible LMCT emission directly observable in the presence of uranyl(VI)

S. D. Woodall, A. N. Swinburne, N. lal Banik, A. Kerridge, P. Di Pietro, C. Adam, P. Kaden and L. S. Natrajan, Chem. Commun., 2015, 51, 5402 DOI: 10.1039/C4CC08718F

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