Issue 11, 2015
From the journal:

Chemical Communications

A Rh-catalyzed 1,2-sulfur migration/aza-Diels–Alder cascade initiated by aza-vinyl carbenoids from sulfur-tethered N-sulfonyl-1,2,3-triazoles†

Yu Jiang,a   Xiang-Ying Tang*b  and  Min Shi*ab  

* Corresponding authors

a Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology, Meilong Road No. 130, Shanghai, China

b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China
E-mail: siocxiangying@mail.sioc.ac.cn, mshi@mail.sioc.ac.cn

Abstract

A novel Rh(II) catalyzed intramolecular 1,2-sulfur rearrangement/intermolecular aza-Diels–Alder cascade initiated by azavinyl carbenes has been developed, efficiently affording sulfur-containing tetrahydropyridine derivatives or α,β-unsaturated imines with a broad substrate scope.

Graphical abstract: A Rh-catalyzed 1,2-sulfur migration/aza-Diels–Alder cascade initiated by aza-vinyl carbenoids from sulfur-tethered N-sulfonyl-1,2,3-triazoles

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C4CC08829H
Article type
Communication
Submitted
05 Nov 2014
Accepted
13 Dec 2014
First published
17 Dec 2014

Chem. Commun., 2015,51, 2122-2125

Author version available

Download author version (PDF)

Permissions

Request permissions

A Rh-catalyzed 1,2-sulfur migration/aza-Diels–Alder cascade initiated by aza-vinyl carbenoids from sulfur-tethered N-sulfonyl-1,2,3-triazoles

Y. Jiang, X. Tang and M. Shi, Chem. Commun., 2015, 51, 2122 DOI: 10.1039/C4CC08829H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements