Issue 8, 2015
From the journal:

Chemical Communications

Diferrocenyl tosyl hydrazone with an ultrastrong NH⋯Fe hydrogen bond as double click switch†

Christoph Förster,a   Philipp Veit,a   Vadim Ksenofontova  and  Katja Heinze*a  

* Corresponding authors

a Institute of Inorganic Chemistry and Analytical Chemistry, Johannes Gutenberg-University of Mainz, Duesbergweg 10-14, 55128 Mainz, Germany
E-mail: katja.heinze@uni-mainz.de
Fax: +49-6131-39-27277
Tel: +49-6131-39-25886

Abstract

The ultrastrong and short intramolecular NH⋯Fe hydrogen bond in diferrocenyl hydrazone 2 raises the barrier for intramolecular electron transfer in its mixed-valent cation 2+ and is only disrupted by double oxidation to 22+.

Graphical abstract: Diferrocenyl tosyl hydrazone with an ultrastrong NH⋯Fe hydrogen bond as double click switch

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C4CC08868A
Article type
Communication
Submitted
06 Nov 2014
Accepted
03 Dec 2014
First published
11 Dec 2014
This article is Open Access
Creative Commons BY license

Chem. Commun., 2015,51, 1514-1516

Permissions

Request permissions

Diferrocenyl tosyl hydrazone with an ultrastrong NH⋯Fe hydrogen bond as double click switch

C. Förster, P. Veit, V. Ksenofontov and K. Heinze, Chem. Commun., 2015, 51, 1514 DOI: 10.1039/C4CC08868A

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements