Issue 10, 2015
From the journal:

Chemical Communications

Targeted synthesis of a large triazine-based [4+6] organic molecular cage: structure, porosity and gas separation†

Huimin Ding,‡a   Yihui Yang,‡a   Bijian Li,a   Feng Pan,a   Guozhu Zhu,a   Matthias Zeller,c   Daqiang Yuan ORCID logo *b  and  Cheng Wang*a  

* Corresponding authors

a Key Laboratory of Biomedical Polymers (Ministry of Education), College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China
E-mail: chengwang@whu.edu.cn

b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
E-mail: ydq@fjirsm.ac.cn

c Department of Chemistry, Youngstown State University, One University Plaza, Youngstown, Ohio 44555, USA

Abstract

Herein, we report the targeted synthesis and solid state assembly of a novel triazine-based [4+6] organic molecular cage. The tetrahedral cage features a large cavity (∼2070 Å3), and after desolvation, the resultant material exhibits a high Brunauer–Emmett–Teller surface area of 1181 m2 g−1 and also features selective adsorption of CO2 over N2.

Graphical abstract: Targeted synthesis of a large triazine-based [4+6] organic molecular cage: structure, porosity and gas separation

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Article information

DOI
https://doi.org/10.1039/C4CC08883B
Article type
Communication
Submitted
06 Nov 2014
Accepted
16 Dec 2014
First published
16 Dec 2014

Chem. Commun., 2015,51, 1976-1979

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Targeted synthesis of a large triazine-based [4+6] organic molecular cage: structure, porosity and gas separation

H. Ding, Y. Yang, B. Li, F. Pan, G. Zhu, M. Zeller, D. Yuan and C. Wang, Chem. Commun., 2015, 51, 1976 DOI: 10.1039/C4CC08883B

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