Issue 7, 2015
From the journal:

Chemical Communications

Nickel-catalysed synthesis of tetrasubstituted vinyl sulfides from thiocarbamates and internal alkynes†

Tasuku Inami,a   Takuya Kurahashi*ab  and  Seijiro Matsubara*a  

* Corresponding authors

a Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyotodaigaku-Katsura, Nishikyo-ku, Kyoto 615-8510, Japan
E-mail: kurahashi.taskuya.2c@kyoto-u.ac.jp, matsubara.seijiro.2e@kyoto-u.ac.jp
Fax: +81 75 383 2438
Tel: +81 75 383 2440

b JST, ACT-C, 4-1-8 Honcho, Kawaguchi, Saitama 332-0012, Japan

Abstract

The thiocarbamoylation of internal alkynes to produce tetrasubstituted β-aminocarbonyl vinyl sulfides was demonstrated using a nickel catalyst. This reaction was successful with a wide variety of substituents, and gave the syn-adducts exclusively.

Graphical abstract: Nickel-catalysed synthesis of tetrasubstituted vinyl sulfides from thiocarbamates and internal alkynes

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Article information

DOI
https://doi.org/10.1039/C4CC09123J
Article type
Communication
Submitted
15 Nov 2014
Accepted
27 Nov 2014
First published
05 Dec 2014

Chem. Commun., 2015,51, 1285-1288

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Nickel-catalysed synthesis of tetrasubstituted vinyl sulfides from thiocarbamates and internal alkynes

T. Inami, T. Kurahashi and S. Matsubara, Chem. Commun., 2015, 51, 1285 DOI: 10.1039/C4CC09123J

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