On the basis of the Diels–Alder reaction of graphite and tetracyanoethylene, graphite has been mechanically exfoliated into graphene adducts in a yield up to 38%. The graphene adduct can restore its conjugated structure via retro-Diels–Alder reaction under mild conditions, exhibiting a high conductivity of 1035 S m−1.
Z. Ji, J. Chen, L. Huang and G. Shi, Chem. Commun., 2015, 51, 2806 DOI: 10.1039/C4CC09144B
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