Organometallic polyphosphorus and -arsenic ligands as linkers between pre-assembled linear CuI fragments

Martin Fleischmann; Luis Dütsch; Mehdi Elsayed Moussa; Andrea Schindler; Gábor Balázs; Christophe Lescop; Manfred Scheer

doi:10.1039/C4CC09845E

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Organometallic polyphosphorus and -arsenic ligands as linkers between pre-assembled linear Cu^I fragments†

Martin Fleischmann,^a Luis Dütsch,^a Mehdi Elsayed Moussa,^b Andrea Schindler,^a Gábor Balázs,^a Christophe Lescop*^b and Manfred Scheer*^a

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* Corresponding authors

^a Institute of Inorganic Chemistry, University of Regensburg, D-93040 Regensburg, Germany
E-mail: manfred.scheer@ur.de
Fax: +49 941 943 4439
Tel: +49 941 943 4440

^b Institut des Sciences Chimiques de Rennes, UMR 6226 CNRS-Université de Rennes 1, Campus de Beaulieu, 35042 Rennes Cedex, France
E-mail: christophe.lescop@univ-rennes1.fr
Fax: +33-2-23-23-69-39
Tel: +33-2-23-23-50-02

Abstract

A simple and straightforward synthesis of a new linear trinuclear Cu^I cluster with polyphosphine ligands is presented. The reaction of this pre-organized Cu₃ precursor with E_n ligand complexes (E = P, As; n = 2, 5) affords discrete complexes exhibiting end-on η¹-coordination of the E₂ ligands or one-dimensional coordination polymers featuring σ-1,3-bridging E₅ rings, respectively.

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DOI: https://doi.org/10.1039/C4CC09845E
Article type: Communication
Submitted: 09 Dec 2014
Accepted: 02 Jan 2015
First published: 05 Jan 2015

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Chem. Commun., 2015,51, 2893-2895

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Organometallic polyphosphorus and -arsenic ligands as linkers between pre-assembled linear Cu^I fragments

M. Fleischmann, L. Dütsch, M. E. Moussa, A. Schindler, G. Balázs, C. Lescop and M. Scheer, Chem. Commun., 2015, 51, 2893 DOI: 10.1039/C4CC09845E

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