This work describes the design and application of a single-pot, reductive arene C–H silanolization of aromatic esters for synthesis of ortho-formyl arylsilanols. This strategy involves a sequence of two transition metal (Ir and Rh)-catalyzed reactions for reductive arene ortho-silylation directed by hydridosilyl acetals and hydrolysis.
Y. Hua, P. Asgari, U. S. Dakarapu and J. Jeon, Chem. Commun., 2015, 51, 3778 DOI: 10.1039/C4CC09850A
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