Issue 22, 2015
From the journal:

Chemical Communications

A reversible two-electron redox system involving a divalent lead species†‡

Masaichi Saito,*a   Marisa Nakada,a   Takuya Kuwabaraa  and  Mao Minourab  

* Corresponding authors

a Department of Chemistry, Graduate School of Science and Engineering, Saitama University, Shimo-okubo, Sakura-ku, Saitama-city, Saitama, Japan
E-mail: masaichi@chem.saitama-u.ac.jp

b Department of Chemistry, Graduate School of Science, Rikkyo University, Nishi-ikebukuro, Toshima-ku, Tokyo, Japan

Abstract

Reduction of THF-stabilized plumbacyclopentadienylidene with lithium afforded dilithioplumbole. On the other hand, oxidation of the dilithioplumbole provided the starting plumbacyclopentadienylidene. This is the unprecedented example of a reversible interconversion between group 14 M(II) and its dianionic species bearing organic substituents.

Graphical abstract: A reversible two-electron redox system involving a divalent lead species

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Article information

DOI
https://doi.org/10.1039/C4CC09856K
Article type
Communication
Submitted
10 Dec 2014
Accepted
06 Feb 2015
First published
10 Feb 2015

Chem. Commun., 2015,51, 4674-4676

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A reversible two-electron redox system involving a divalent lead species

M. Saito, M. Nakada, T. Kuwabara and M. Minoura, Chem. Commun., 2015, 51, 4674 DOI: 10.1039/C4CC09856K

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