Ligation driven 19F relaxation enhancement in self-assembled Ln(III) complexes

Gemma-Louise Davies; Asha Brown; Octavia Blackburn; Manuel Tropiano; Stephen Faulkner; Paul D. Beer; Jason J. Davis

doi:10.1039/C4CC09952D

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Ligation driven ¹⁹F relaxation enhancement in self-assembled Ln(iii) complexes†

Gemma-Louise Davies,‡^a Asha Brown,^a Octavia Blackburn,^a Manuel Tropiano,^a Stephen Faulkner,^a Paul D. Beer^a and Jason J. Davis*^a

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* Corresponding authors

^a Department of Chemistry, University of Oxford, South Parks Road, Oxford, UK
E-mail: Jason.davis@chem.ox.ac.uk
Fax: +44 (0)1865 272 690
Tel: +44 (0)1865 275 914

Abstract

Strong bidentate ligation between a fluorinated isophthalate and binuclear lanthanide-DO3A species yields a new class of ¹⁹F NMR agent with very high nuclear relaxation rates at physiologically-relevant pH.

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Article information

DOI: https://doi.org/10.1039/C4CC09952D
Article type: Communication
Submitted: 13 Dec 2014
Accepted: 21 Dec 2014
First published: 22 Dec 2014

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Chem. Commun., 2015,51, 2918-2920

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Ligation driven ¹⁹F relaxation enhancement in self-assembled Ln(III) complexes

G. Davies, A. Brown, O. Blackburn, M. Tropiano, S. Faulkner, P. D. Beer and J. J. Davis, Chem. Commun., 2015, 51, 2918 DOI: 10.1039/C4CC09952D

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