Issue 17, 2015
From the journal:

Chemical Communications

Facile synthesis of magnetic homochiral metal–organic frameworks for “enantioselective fishing”†

Cui-Lan Chang,‡a   Xiao-Yue Qi,‡a   Jiang-Wei Zhang,b   Ya-Ming Qiu,c   Xian-Jiang Li,a   Xin Wang,a   Yu Bai,a   Jun-Liang Sunc  and  Hu-Wei Liu*a  

* Corresponding authors

a Beijing National Laboratory for Molecular Sciences, Institute of Analytical Chemistry, College of Chemistry and Molecular Engineering, Peking University, Beijing, China
E-mail: hwliu@pku.edu.cn
Tel: +86-10-62754976

b Department of Chemistry, Tsinghua University, Beijing, China

c Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing, China

Abstract

Magnetic functionalized homochiral metal–organic frameworks (MOFs) were prepared and applied to efficient enantioselective fishing of chiral drug intermediates. Under optimized conditions, the enantiomeric excess (ee) value as high as 85.2% was achieved for methyl phenyl sulfoxide (MPS) within 3 min.

Graphical abstract: Facile synthesis of magnetic homochiral metal–organic frameworks for “enantioselective fishing”

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Article information

DOI
https://doi.org/10.1039/C4CC09988E
Article type
Communication
Submitted
15 Dec 2014
Accepted
22 Jan 2015
First published
22 Jan 2015

Chem. Commun., 2015,51, 3566-3569

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Facile synthesis of magnetic homochiral metal–organic frameworks for “enantioselective fishing”

C. Chang, X. Qi, J. Zhang, Y. Qiu, X. Li, X. Wang, Y. Bai, J. Sun and H. Liu, Chem. Commun., 2015, 51, 3566 DOI: 10.1039/C4CC09988E

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