Issue 18, 2015

Metal-free radical oxidative decarboxylation/cyclization of acyl peroxides and 2-isocyanobiphenyls

Abstract

A metal-free radical oxidative decarboxylation/cyclization of acyl peroxides and 2-isocyanobiphenyls was achieved, leading to 6-aryl phenanthridines as well as 6-alkyl phenanthridines in moderate to good yields. The procedure featured simple conditions and was metal-free and base free. It represents a practical approach to access 6-aryl/alkyl phenanthridines.

Graphical abstract: Metal-free radical oxidative decarboxylation/cyclization of acyl peroxides and 2-isocyanobiphenyls

Supplementary files

Article information

Article type
Communication
Submitted
16 Dec 2014
Accepted
16 Jan 2015
First published
16 Jan 2015

Chem. Commun., 2015,51, 3786-3788

Metal-free radical oxidative decarboxylation/cyclization of acyl peroxides and 2-isocyanobiphenyls

C. Pan, H. Zhang, J. Han, Y. Cheng and C. Zhu, Chem. Commun., 2015, 51, 3786 DOI: 10.1039/C4CC10015H

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