Issue 18, 2015
From the journal:

Chemical Communications

Efficient electrochemiluminescence of a readily accessible boron difluoride formazanate dye†

Mahdi Hesari,a   Stephanie M. Barbon,a   Viktor N. Staroverov,a   Zhifeng Ding*a  and  Joe B. Gilroy*a  

* Corresponding authors

a Department of Chemistry and the Centre for Advanced Materials and Biomaterials Research (CAMBR), The University of Western Ontario, London, Ontario, Canada
E-mail: zfding@uwo.ca, joe.gilroy@uwo.ca

Abstract

Electrochemiluminescence (ECL) of a boron difluoride formazanate dye was investigated in the presence of tri-n-propylamine as a reductive co-reactant. The ECL mechanism was studied using ECL-voltage curves, spooling ECL, and accumulative ECL spectroscopy. The ECL occurs at 724 nm by three distinct, voltage-dependent mechanisms of light emission.

Graphical abstract: Efficient electrochemiluminescence of a readily accessible boron difluoride formazanate dye

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Article information

DOI
https://doi.org/10.1039/C4CC10038G
Article type
Communication
Submitted
16 Dec 2014
Accepted
27 Jan 2015
First published
03 Feb 2015

Chem. Commun., 2015,51, 3766-3769

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Efficient electrochemiluminescence of a readily accessible boron difluoride formazanate dye

M. Hesari, S. M. Barbon, V. N. Staroverov, Z. Ding and J. B. Gilroy, Chem. Commun., 2015, 51, 3766 DOI: 10.1039/C4CC10038G

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