Synthesis, structure and properties of C3-symmetric heterosuperbenzene with three BN units

Xiao-Ye Wang; Fang-Dong Zhuang; Xin-Chang Wang; Xiao-Yu Cao; Jie-Yu Wang; Jian Pei

doi:10.1039/C4CC10105G

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Synthesis, structure and properties of C₃-symmetric heterosuperbenzene with three BN units†

Xiao-Ye Wang,^a Fang-Dong Zhuang,^a Xin-Chang Wang,^b Xiao-Yu Cao,*^b Jie-Yu Wang*^a and Jian Pei*^a

Author affiliations

* Corresponding authors

^a Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, Center for Soft Matter Science and Engineering, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China
E-mail: jieyuwang@pku.edu.cn, jianpei@pku.edu.cn

^b College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, P. R. China
E-mail: xcao@xmu.edu.cn

Abstract

The parent skeleton of BN heterocoronene with three BN units and C₃ symmetry was synthesized as a model compound of BN-doped graphene. Further investigation of this graphene-type molecule revealed the important role of BN doping in opening the bandgap and modulating the electronic properties.

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Article information

DOI: https://doi.org/10.1039/C4CC10105G
Article type: Communication
Submitted: 18 Dec 2014
Accepted: 09 Jan 2015
First published: 09 Jan 2015

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Chem. Commun., 2015,51, 4368-4371

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Synthesis, structure and properties of C₃-symmetric heterosuperbenzene with three BN units

X. Wang, F. Zhuang, X. Wang, X. Cao, J. Wang and J. Pei, Chem. Commun., 2015, 51, 4368 DOI: 10.1039/C4CC10105G

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